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- researchproject type ResearchProject assertion.
- researchproject label "ANR-DFG project SHIELDS" assertion.
- researchproject seeAlso shields assertion.
- researchproject description "Hydrogel shields to support and protect catalysts of H2 oxidation and CO2 reduction - The use of metalloenzymes or synthetic inorganic complexes as catalysts in fuels cells or photoelectrochemical cells may open key routes in energy production and in industrial synthesis. However, the intrinsic fragility and oxygen sensitivity of these catalysts has been an obstacle. Hydrogenases, the very efficient but very fragile biological catalysts of H2 oxidation, could be protected from O2 damage upon integration into a specifically designed redox hydrogel, which reduces oxygen at the polymer surface and thus provides self-activated protection from oxygen [Plumeré et al, Nature Chemistry, 2014]. We could also rationalise the protection mechanism and optimise the design of the catalyst-polymer films [Fourmond et al, J. Am. Chem Soc., 2015]. These results have set the stage for the full investigation that is the goal of this ANR/DFG project (https://redox-shields.org/shields/)" assertion.
- researchproject has-research-domain NCIT_C16414 assertion.
- researchproject has-research-domain topic_3370 assertion.
- researchproject has-research-domain topic_3297 assertion.
- researchproject sameAs-def "ANR-DFG number PL 746/2–1" assertion.
- researchproject sameAs-def "ERC Starting Grant number 715900" assertion.
- researchproject endDate "2022" assertion.
- researchproject funder 00rbzpz17 assertion.
- researchproject funder 018mejw64 assertion.
- researchproject funder 0472cxd90 assertion.
- researchproject startDate "2019" assertion.